Material safety data sheet msds is a document that contains information on the potential. We accept custom synthesis of compounds not shown in the list. Phosgene is toxic and exposure in the workplace should be stringently avoided. Formerly known as material safety data sheets, phac now refers to them as pathogen safety data sheets or psdss. It compiles information from several government agencies and organizations. Material safety data sheet product name phosfree commercial. Determination of phosgene in air samples using thermal desorption td followed by gas chromatographymass spectrometry gcms has been reported.
Phosgene can form in chloroform as it is exposed to oxygen and amounts of uv light although uv light is not always necessary if catalytic contaminants are present. Exposure to phosgene may cause irritation to the eyes, dry burning throat, vomiting, cough, foamy sputum, breathing difficulty, and chest pain. Material safety data sheet lumefantrine sc207836 hazard alert code key. Phosphine as this product is a gas, refer to the inhalation section. No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or. The following section has been provided to help users identify some regulatory information directly related to phosgene. Safety data sheet according to ec directive 200159ec and oshas hazcom standard 29 cfr 1910. Section 6 accidental release measures clean up spills immediately, observing precautions in section 8 of this document. Country usa % by weight hazard symbol 515 none 515 none skin. Phosgene is a suitable reagent for converting secondary amides,351,352 and nunsubstituted lactams 353 to imide chlorides, e. Material safety data sheet keystone pest solutions. Phosgenefree dimethyl carbonate production fick, lin, vavra 4 the purpose of this project is to design a chemical process which employs a new phosgene free reaction to produce 100 million pounds of dimethyl carbonate dmc. Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Diphosgene is related to phosgene and has comparable toxicity, but is more conveniently handled because it is a liquid, whereas phosgene is a gas. Free msds or sds search site millions of free msds sheets. It is the responsibility of each person shipping, transporting or using phosgene to know and to comply with all applicable laws and regulations pertaining to shipping, labeling and placarding. Monomethylamine msds search our sds online database free. Protective equipment and precautions for firefighters as in any fire, wear selfcontained breathing apparatus pressuredemand, mshaniosh approved or equivalent and full protective gear.
Extreme high moderate low section 1 chemical product and company identification product name lumefantrine statement of hazardous nature considered a hazardous substance according to osha 29 cfr 1910. Osha occupational chemical database occupational safety and. Warning properties of the gas inhaled are slight, death may occur within 36. Diphosgene is a chemical compound with the formula clco 2 ccl 3. The cse also searches any query for osha standards, just enter the question or reg. Chloroform and phosgene, chemical hygiene and safety. Acute oral ld50 rat 280 mgkg dermal ld50 rat 2,000 mgkg inhalation lc50 rat 0. Breathing phosgene can irritate the lungs causing coughing andor shortness of breath. Material safety data sheet qualipro 2d page 1 of 4 12. It is the responsibility of each person shipping, transporting or using phosgene to know and to comply with all applicable laws and. Phosgene is formed during the free radical induced degradation of chlorinated hydrocarbons. The major pathological feature is delayed pulmonary edema. It is not intended to be a comprehensive treatise on the chemical or toxicological nature of phosgene.
Phosgene appears as a colorless gas or very lowboiling, volatile liquid b. Search the cse for all free sds msds sheets available on the web. Phosgene carbonyl chloride cas 75445 ghs chemical container label. Accidental release measures clean up spills immediately observing the precautions in section 8 of this msds. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. Phosgene is a valued industrial building block, especially for the production of urethanes and polycarbonate plastics.
Phosgene is an insidious poison as the odor may not be noticed and symptoms may be slow to appear. Keep product and empty container away from heat and sources of ignition. Safety data sheets free sds database chemical safety. Signs and symptoms of toxicity may be delayed for 24 hours. Firstaid measures first aid measures general advice when possible, have the product container or label with you when calling a poison control center or doctor or going for treatment.
Chronic exposure to phosgene compounds may cause irreversible pulmonary. Tested to withstand exposure to acetone, dichloromethane, hydrofluoric acid. Locating and estimating air emission from sources of phosgene. Phosgene is the organic chemical compound with the formula cocl 2. This colorless liquid is a valuable reagent in the synthesis of organic compounds.
There is no evidence that paraquat 3sl is mutagenic or teratogenic at doses below 150 mgkgday. Phosgene is an acyl chloride obtained by substitution of both hydrogens of formaldehyde by chlorine. Phosgene is an extremely versatile reagent allowing easy access to isocyanates, ureas, carbamates, carbonates, acyl and alkyl chlorides. Isolate the hazard area and keep unnecessary and unprotected personnel from entering. Usdot 2008 emergency response guidebook initial response information for 4 related materials. Dependable 3m adhesive vinyl that is built to resist harsh conditions. Although the panel makes every effort to be accurate, as with other sections of the guidelines, no representations or warranties. Code of federal regulations title 49 section 172 shipping regulations and 2 proper shipping names. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy.
Phosgene is a major industrial chemical used to make plastics and pesticides. Material safety data sheet page 1 of 3 product name. Like many reactive chlorides, phosgene combines with water in the tissues of the respiratory tract to form hydrochloric acid. This handout provides information and followup instructions for persons who have been exposed to phosgene. Thermal decomposition can lead to release of irritating gases and vapors. Hydrogen bromide hydrogen chloride hydrogen fluoride carbonyl halides free halogens phosgene. Phosgene phg cautionary response information common synonyms liquefied compressed gas colorless gas, or light yellow liquid sweet or sharp odor liquid sinks in.
Osha occupational chemical database occupational safety. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Breathing phosgene can irritate the nose and throat. Carbon dioxide, carbon monoxide, various hydrocarbons and small amounts of phosgene.
This page introduces phosgene derivative products we handle. Phosgene is a common chemical intermediate utilized in the synthesis of numerous chemical intermediates used to produce pharmaceutical active ingredients, monomers for various polymers, pesticides, herbicides and other specialty chemicals. Carbon monoxide is added in stoichiometric excess to keep the free chlorine. As a dehydrating agent, phosgene can also lead to isocyanides, cyanides, and carbodiimides. With cooling and pressure, phosgene gas can be converted into a liquid so that it can be shipped and stored. Carbon monoxide co carbon dioxide co2 hydrogen chloride gas phosgene. This chemical inventory is oshas premier onestop shop for occupational chemical information. Chemical properties of phosgene cas 75445 download as pdf file download as excel file download as 2d mole file predict properties. Phosgene is a corrosive chemical and contact can severely irritate and burn the skin and eyes. Certain features of will be unavailable due to maintenance from saturday morning, april 25th at 9. However, it is very poisonous and was used as a chemical weapon during world war i where it was responsible for. With cooling and pressure, phosgene gas can be changed into a liquid so that it can be shipped and stored. When liquid phosgene is released, it quickly turns into a gas that stays close to the ground and.
The substituents at nitrogen might be saturated aliphatic or aromatic groups, but even unsaturated groups seem to be possible. Cdc niosh pocket guide to chemical hazards phosgene. Phosgene is stable when stored in dry steel containers phosgene is a member of a class of organic chemicals. This page contains information on the chemical phosgene including.
In section 6, major conclusions in the characterization of hazard and dose response. The international hazard communication standard hcs mandates that chemical manufacturers must communicate a chemicals hazard information to chemical handlers by providing a safety data sheet. To see more msds documents from our industryleading safety data sheet sds database use our msds search tool. A safety data sheet, or sds, is a standardized document that contains occupational safety and health data. Phosgene 75445 yes yes yes yes yes yes not regulated under california proposition 65. Durable laminate that increases the label strength and resistance. When liquid phosgene is released, it quickly turns into a gas that stays close to the ground and spreads rapidly. Siri has over 500,000 free hard to find msds sheets. Phosgene cocl2 is a toxic gasliquid used as a chemical warfare agent during wwi. Phosgene cocl2 or ccl2o cid 6371 structure, chemical names, physical and. Phosgene is a lung toxicant that causes damage to the capillaries, bronchioles and alveoli of the lungs, by decomposition to hydrochloric acid.
Chemical identification and physical properties exposure limits sampling information. Carbon dioxide co2 safety data sheet sds p4574 log in. The information provided in this safety data sheet is correct to the best of our knowledge, information and belief at the date of its publication. It plays a role in how your page is seen by search engine crawlers, and how it appears in serps. A meta description is an html tag in the html code of your website, which allows you to customize a section of text that describes the page itself.
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